The service life of a lithium-ion battery is influenced by cyclical ageing and calendar ageing.
The extent to which a cell ages due to cyclical ageing depends largely on the load intensity, the discharge and charge current, the depth of discharge (DoD) and the ambient temperature. Cyclical ageing can be determined by simple tests in which the battery is continuously discharged and charged at defined parameters. If the battery falls below a certain characteristic value, for example if the aged residual capacity is between 70... 80 % of the nominal capacity, the battery has reached the end of its service life.
In order to investigate the service life of a battery for a sub-sea project, multi-channel charging and discharging electronics were developed, which are controlled via a DAQ system with LabView. This makes it possible to measure the currents, voltages and temperatures precisely and quickly and save them for later analysis. Several test groups are used to age cell groups differently and compare and analyze the aging effects.
Further investigations/analyses of the cell are carried out using electrochemical impedance spectroscopy. The aim is to analyze various aging effects more clearly and, in a further step, provide the basis for a battery management system.